The substantional composition of sediments of lower-devonian red-colour terrigenous subformation of Volyno-Podillya, that was formed in the different facial zones of paleobasin – river-beds, holms, oxbows of alluvial plain, in oxidative and reductive environments, is investigated. The hydrodynamic conditions of environments played a pivotal role in forming of sediments in the different environments of accumulation of them in Dniesterian paleobasin.

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